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In order to identify the value orientations of adolescents and the role of the Orthodox Church in the formation of value-semantic attitudes in adolescents with deviant behavior, a clinical and psychological study of minors who are being treated in the Chelyabinsk regional narcological hospital was conducted. The work was carried out during the period when the teenagers were in a drug treatment hospital in the form of individual conversations and consultations, group conversations, games, contests, and quizzes with a specific thematic focus. The analysis of the results made it possible to identify the emerging values and foundations of the worldview, as well as the features of value-semantic attitudes. According to the results of the teenagers' stay in the drug treatment hospital, positive changes were noted in the studied personality structure.